Geological Observations on South America

SUPERFICIAL SALINE DEPOSITS.

This subject may be here conveniently treated of: I will begin with the most interesting case, namely, the superficial saline beds near Iquique in Peru. The porphyritic mountains on the coast rise abruptly to a height of between one thousand nine hundred and three thousand feet: between their summits and an inland plain, on which the celebrated deposit of nitrate of soda lies, there is a high undulatory district, covered by a remarkable superficial saliferous crust, chiefly composed of common salt, either in white, hard, opaque nodules, or mingled with sand, in this latter case forming a compact sandstone. This saliferous superficial crust extends from the edge of the coast-escarpment, over the whole face of the country; but never attains, as I am assured by Mr. Bollaert (long resident here) any great thickness. Although a very slight shower falls only at intervals of many years, yet small funnel-shaped cavities show that the salt has been in some parts dissolved. (It is singular how slowly, according to the observations of M. Cordier on the salt-mountain of Cardona in Spain "Ann. des Mines, Translation of Geolog. Mem." by De la Beche page 60, salt is dissolved, where the amount of rain is supposed to be as much as 31.4 of an inch in the year. It is calculated that only five feet in thickness is dissolved in the course of a century.) In several places I saw large patches of sand, quite moist, owing to the quantity of muriate of lime (as ascertained by Mr. T. Reeks) contained in them. From the compact salt- cemented sand being either red, purplish, or yellow, according to the colour of the rocky strata on which it rested, I imagined that this substance had probably been derived through common alluvial action from the layers of salt which occur interstratified in the surrounding mountains ("Journal of Researches" page 444 first edition.): but from the interesting details given by M. d'Orbigny, and from finding on a fresh examination of this agglomerated sand, that it is not irregularly cemented, but consists of thin layers of sand of different tints of colour, alternating with excessively fine parallel layers of salt, I conclude that it is not of alluvial origin. M. d'Orbigny observed analogous saline beds extending from Cobija for five degrees of latitude northward, and at heights varying from six hundred to nine hundred feet ("Voyage" etc. page 102. M. d'Orbigny found this deposit intersected, in many places, by deep ravines, in which there was no salt. Streams must once, though historically unknown, have flowed in them; and M. d'Orbigny argues from the presence of undissolved salt over the whole surrounding country, that the streams must have arisen from rain or snow having fallen, not in the adjoining country, but on the now arid Cordillera. I may remark, that from having observed ruins of Indian buildings in absolutely sterile parts of the Chilian Cordillera ("Journal" 2nd edition page 357), I am led to believe that the climate, at a time when Indian man inhabited this part of the continent, was in some slight degree more humid than it is at present.): from finding recent sea- shells strewed on these saliferous beds, and under them, great well-rounded blocks, exactly like those on the existing beach, he believes that the salt, which is invariably superficial, has been left by the evaporation of the sea-water. This same conclusion must, I now believe, be extended to the superficial saliferous beds of Iquique, though they stand about three thousand feet above the level of the sea.

Associated with the salt in the superficial beds, there are numerous, thin, horizontal layers of impure, dirty-white, friable, gypseous and calcareous tuffs. The gypseous beds are very remarkable, from abounding with, so as sometimes to be almost composed of, irregular concretions, from the size of an egg to that of a man's head, of very hard, compact, heavy gypsum, in the form of anhydrite. This gypsum contains some foreign particles of stone; it is stained, judging from its action with borax, with iron, and it exhales a strong aluminous odour. The surfaces of the concretions are marked by sharp, radiating, or bifurcating ridges, as if they had been (but not really) corroded: internally they are penetrated by branching veins (like those of calcareous spar in the septaria of the London clay) of pure white anhydrite. These veins might naturally have been thought to have been formed by subsequent infiltration, had not each little embedded fragment of rock been likewise edged in a very remarkable manner by a narrow border of the same white anhydrite: this shows that the veins must have been formed by a process of segregation, and not of infiltration. Some of the little included and CRACKED fragments of foreign rock are penetrated by the anhydrite, and portions have evidently been thus mechanically displaced: at St. Helena, I observed that calcareous matter, deposited by rain water, also had the power to separate small fragments of rock from the larger masses. ("Volcanic Islands" etc. page 87.) I believe the superficial gypseous deposit is widely extended: I received specimens of it from Pisagua, forty miles north of Iquique, and likewise from Arica, where it coats a layer of pure salt. M. d'Orbigny found at Cobija a bed of clay, lying above a mass of upraised recent shells, which was saturated with sulphate of soda, and included thin layers of fibrous gypsum. ("Voyage Geolog." etc. page 95.) These widely extended, superficial, beds of salt and gypsum, appear to me an interesting geological phenomenon, which could be presented only under a very dry climate.

The plain or basin, on the borders of which the famous bed of nitrate of soda lies, is situated at the distance of about thirty miles from the sea, being separated from it by the saliferous district just described. It stands at a height of 3,300 feet; its surface is level, and some leagues in width; it extends forty miles northward, and has a total length (as I was informed by Mr. Belford Wilson, the Consul-General at Lima) of 420 miles. In a well near the works, thirty-six yards in depth, sand, earth, and a little gravel were found: in another well, near Almonte, fifty yards deep, the whole consisted, according to Mr. Blake, of clay, including a layer of sand two feet thick, which rested on fine gravel, and this on coarse gravel, with large rounded fragments of rock. (See an admirable paper "Geological and Miscellaneous Notices of Tarapaca" in "Silliman's American Journal" volume 44 page 1.) In many parts of this now utterly desert plain, rushes and large prostrate trees in a hardened state, apparently Mimosas, are found buried, at a depth from three to six feet; according to Mr. Blake, they have all fallen to the south-west. The bed of nitrate of soda is said to extend for forty to fifty leagues along the western margin of the plain, but is not found in its central parts: it is from two to three feet in thickness, and is so hard that it is generally blasted with gunpowder; it slopes gently upwards from the edge of the plain to between ten and thirty feet above its level. It rests on sand in which, it is said, vegetable remains and broken shells have been found; shells have also been found, according to Mr. Blake, both on and in the nitrate of soda. It is covered by a superficial mass of sand, containing nodules of common salt, and, as I was assured by a miner, much soft gypseous matter, precisely like that in the superficial crust already described: certainly this crust, with its characteristic concretions of anhydrite, comes close down to the edge of the plain.

The nitrate of soda varies in purity in different parts, and often contains nodules of common salt. According to Mr. Blake, the proportion of nitrate of soda varies from 20 to 75 per cent. An analysis by Mr. A. Hayes, of an average specimen, gave: —

Nitrate of Soda… 64.98

Sulphate of Soda… 3.00

Chloride of Soda… 28.69

Iodic Salts..... 0.63

Shells and Marl… 2.60

99.90

The "mother-water" at some of the refineries is very rich in iodic salts, and is supposed to contain much muriate of lime. ("Literary Gazette" 1841 page 475.) In an unrefined specimen brought home by myself, Mr. T. Reeks has ascertained that the muriate of lime is very abundant. With respect to the origin of this saline mass, from the manner in which the gently inclined, compact bed follows for so many miles the sinuous margin of the plain, there can be no doubt that it was deposited from a sheet of water: from the fragments of embedded shells, from the abundant iodic salts, from the superficial saliferous crust occurring at a higher level and being probably of marine origin, and from the plain resembling in form those of Chile and that of Uspallata, there can be little doubt that this sheet of water was, at least originally, connected with the sea. (From an official document, shown me by Mr. Belford Wilson, it appears that the first export of nitrate of soda to Europe was in July 1830, on French account, in a British ship: —

In year, the entire export was in Quintals.

1830............... 17,300

1831............... 40,885

1832............... 51,400

1833............... 91,335

1834............... 149,538

The Spanish quintal nearly equals 100 English pounds.)

THIN, SUPERFICIAL, SALINE INCRUSTATIONS.

These saline incrustations are common in many parts of America: Humboldt met with them on the tableland of Mexico, and the Jesuit Falkner and other authors state that they occur at intervals over the vast plains extending from the mouth of the Plata to Rioja and Catamarca. (Azara "Travels" volume 1 page 55, considers that the Parana is the eastern boundary of the saliferous region; but I heard of "salitrales" in the Province of Entre Rios.) Hence it is that during droughts, most of the streams in the Pampas are saline. I nowhere met with these incrustations so abundantly as near Bahia Blanca: square miles of the mud-flats, which near that place are raised only a few feet above the sea, just enough to protect them from being overflowed, appear, after dry weather, whiter than the ground after the thickest hoar-frost. After rain the salts disappear, and every puddle of water becomes highly saline; as the surface dries, the capillary action draws the moisture up pieces of broken earth, dead sticks, and tufts of grass, where the salt effloresces. The incrustation, where thickest, does not exceed a quarter of an inch. M. Parchappe has analysed it (M. d'Orbigny "Voyage" etc. Part. Hist. tome 1 page 664.); and finds that the specimens collected at the extreme head of the low plain, near the River Manuello, consist of 93 per cent of sulphate of soda, and 7 of common salt; whilst the specimens taken close to the coast contain only 63 per cent of the sulphate, and 37 of the muriate of soda. This remarkable fact, together with our knowledge that the whole of this low muddy plain has been covered by the sea within the recent period, must lead to the suspicion that the common salt, by some unknown process, becomes in time changed into the sulphate. Friable, calcareous matter is here abundant, and the case of the apparent double decomposition of the shells and salt on San Lorenzo, should not be forgotten.

The saline incrustations, near Bahia Blanca, are not confined to, though most abundant on, the low muddy flats; for I noticed some on a calcareous plain between thirty and forty feet above the sea, and even a little occurs in still higher valleys. Low alluvial tracts in the valleys of the Rivers Negro and Colorado are also encrusted, and in the latter valley such spaces appeared to be occasionally overflowed by the river. I observed saline incrustations in some of the valleys of Southern Patagonia. At Port Desire a low, flat, muddy valley was thickly incrusted by salts, which on analysis by Mr. T. Reeks, are found to consist of a mixture of sulphate and muriate of soda, with carbonate of lime and earthy matter. On the western side of the continent, the southern coasts are much too humid for this phenomenon; but in Northern Chile I again met with similar incrustations. On the hardened mud, in parts of the broad, flat-bottomed valley of Copiapo, the saline matter encrusts the ground to the thickness of some inches: specimens, sent by Mr. Bingley to Apothecaries' Hall for analysis, were said to consist of carbonate and sulphate of soda. Much sulphate of soda is found in the desert of Atacama. In all parts of South America, the saline incrustations occur most frequently on low damp surfaces of mud, where the climate is rather dry; and these low surfaces have, in almost every case, been upraised above the level of the sea, within the recent period.

SALT-LAKES OF PATAGONIA AND LA PLATA.

Salinas, or natural salt-lakes, occur in various formations on the eastern side of the continent, – in the argillaceo-calcareous deposit of the Pampas, in the sandstone of the Rio Negro, where they are very numerous, in the pumiceous and other beds of the Patagonian tertiary formation, and in small primary districts in the midst of this latter formation. Port S. Julian is the most southerly point (latitude 49 degrees to 50 degrees) at which salinas are known to occur. (According to Azara "Travels" volume 1 page 56, there are salt-lakes as far north as Chaco (latitude 25 degrees), on the banks of the Vermejo. The salt-lakes of Siberia appear (Pallas "Travels" English Translation volume 1 page 284) to occur in very similar depressions to those of Patagonia.) The depressions, in which these salt-lakes lie, are from a few feet to sixty metres, as asserted by M. d'Orbigny, below the surface of the surrounding plains ("Voyage Geolog." page 63.); and, according to this same author, near the Rio Negro they all trend, either in the N.E. and S.W. or in E. and W. lines, coincident with the general slope of the plain. These depressions in the plain generally have one side lower than the others, but there are no outlets for drainage. Under a less dry climate, an outlet would soon have been formed, and the salt washed away. The salinas occur at different elevations above the sea; they are often several leagues in diameter; they are generally very shallow, but there is a deep one in a quartz-rock formation near C. Blanco. In the wet season, the whole, or a part, of the salt is dissolved, being redeposited during the succeeding dry season. At this period the appearance of the snow-white expanse of salt crystallised in great cubes, is very striking. In a large salina, northward of the Rio Negro, the salt at the bottom, during the whole year, is between two and three feet in thickness.

The salt rests almost always on a thick bed of black muddy sand, which is fetid, probably from the decay of the burrowing worms inhabiting it. (Professor Ehrenberg examined some of this muddy sand, but was unable to find in it any infusoria.) In a salina, situated about fifteen miles above the town of El Carmen on the Rio Negro, and three or four miles from the banks of that river, I observed that this black mud rested on gravel with a calcareous matrix, similar to that spread over the whole surrounding plains: at Port S. Julian the mud, also, rested on the gravel: hence the depressions must have been formed anteriorly to, or contemporaneously with, the spreading out of the gravel. I was informed that one small salina occurs in an alluvial plain within the valley of the Rio Negro, and therefore its origin must be subsequent to the excavation of that valley. When I visited the salina, fifteen miles above the town, the salt was beginning to crystallise, and on the muddy bottom there were lying many crystals, generally placed crossways of sulphate of soda (as ascertained by Mr. Reeks), and embedded in the mud, numerous crystals of sulphate of lime, from one to three inches in length: M. d'Orbigny states that some of these crystals are acicular and more than even nine inches in length ("Voyage Geolog." page 64.); others are macled and of great purity: those I found all contained some sand in their centres. As the black and fetid sand overlies the gravel, and that overlies the regular tertiary strata, I think there can be no doubt that these remarkable crystals of sulphate of lime have been deposited from the waters of the lake. The inhabitants call the crystals of selenite, the padre del sal, and those of the sulphate of soda, the madre del sal; they assured me that both are found under the same circumstances in several of the neighbouring salinas; and that the sulphate of soda is annually dissolved, and is always crystallised before the common salt on the muddy bottom. (This is what might have been expected; for M. Ballard asserts "Acad. des Sciences" October 7, 1844, that sulphate of soda is precipitated from solution more readily from water containing muriate of soda in excess, than from pure water.) The association of gypsum and salt in this case, as well as in the superficial deposits of Iquique, appears to me interesting, considering how generally these substances are associated in the older stratified formations.

Mr. Reeks has analysed for me some of the salt from the salina near the Rio Negro; he finds it composed entirely of chloride of sodium, with the exception of 0.26 of sulphate of lime and of 0.22 of earthy matter: there are no traces of iodic salts. Some salt from the salina Chiquitos, in the Pampean formation, is equally pure. It is a singular fact, that the salt from these salinas does not serve so well for preserving meat, as sea-salt from the Cape de Verde Islands; and a merchant at Buenos Ayres told me that he considered it as 50 per cent less valuable. The purity of the Patagonian salt, or absence from it of those other saline bodies found in all sea- water, is the only assignable cause for this inferiority; a conclusion which is supported by the fact lately ascertained, that those salts answer best for preserving cheese which contain most of the deliquescent chlorides. ("Horticultural and Agricultural Gazette" 1845 page 93.) (It would probably well answer for the merchants of Buenos Ayres (considering the great consumption there of salt for preserving meat) to import the deliquescent chlorides to mix with the salt from the salinas: I may call attention to the fact, that at Iquique, a large quantity of muriate of lime, left in the MOTHER-WATER during the refinement of the nitrate of soda, is annually thrown away.)

With respect to the origin of the salt in the salinas, the foregoing analysis seems opposed to the view entertained by M. d'Orbigny and others, and which seems so probable considering the recent elevation of this line of coast, namely, that it is due to the evaporation of sea-water and to the drainage from the surrounding strata impregnated with sea-salt. I was informed (I know not whether accurately) that on the northern side of the salina on the Rio Negro, there is a small brine spring which flows at all times of the year: if this be so, the salt in this case at least, probably is of subterranean origin. It at first appears very singular that fresh water can often be procured in wells, and is sometimes found in small lakes, quite close to these salinas. (Sir W. Parish states "Buenos Ayres" etc. pages 122 and 170, that this is the case near the great salinas westward of the S. Ventana. I have seen similar statements in an ancient MS. Journal lately published by S. Angelis. At Iquique, where the surface is so thickly encrusted with saline matter, I tasted water only slightly brackish, procured in a well thirty-six yards deep; but here one feels less surprise at its presence, as pure water might percolate under ground from the not very distant Cordillera.) I am not aware that this fact bears particularly on the origin of the salt; but perhaps it is rather opposed to the view of the salt having been washed out of the surrounding superficial strata, but not to its having been the residue of sea-water, left in depressions as the land was slowly elevated.