The Evolution of Photography

The Heliographic process of M. Niépce consists of a solution of asphaltum, bitumen of Judea, being spread on metal or glass plates, submitted to the action of light either by superposition or in the camera, and the unaffected parts dissolved away afterwards by means of a suitable solvent. But, in case any student of photography should like to produce one of the first form of permanent sun-pictures, I shall give here the details of M. Niépce’s own modus operandi for preparing the solution of bitumen and coating the plate:—

“I about half fill a wine-glass with this pulverised bitumen; I pour upon it, drop by drop, the essential oil of lavender until the bitumen is completely saturated. I afterwards add as much more of the essential oil as causes the whole to stand about three lines above the mixture, which is then covered and submitted to a gentle heat until the essential oil is fully impregnated with the colouring matter of the bitumen. If this varnish is not of the required consistency, it is to be allowed to evaporate slowly, without heat, in a shallow dish, care being taken to protect it from moisture, by which it is injured and at last decomposed. In winter, or in rainy weather, the precaution is doubly necessary. A tablet of plated silver, or well cleaned and warm glass, is to be highly polished, on which a thin coating of the varnish is to be applied cold, with a light roll of very soft skin; this will impart to it a fine vermilion colour, and cover it with a very thin and equal coating. The plate is then placed upon heated iron, which is wrapped round with several folds of paper, from which, by this method, all moisture had been previously expelled. When the varnish has ceased to simmer, the plate is withdrawn from the heat, and left to cool and dry in a gentle temperature, and protected from a damp atmosphere. In this part of the operation a light disc of metal, with a handle in the centre, should be held before the mouth, in order to condense the moisture of the breath.”

In the foregoing description it will be observed how much importance M. Niépce attached to the necessity of protecting the solution and prepared plate from moisture, and that no precautions are given concerning the effect of white light. It must be remembered, however, that the material employed was very insensitive, requiring many hours of exposure either in the camera or under a print or drawing placed in contact with the prepared surface, and consequently such precaution might not have been deemed necessary. Probably M. Niépce worked in a subdued light, but there can be no doubt about the necessity of conducting both the foregoing operations in yellow light. Had M. Niépce performed his operations in a non-actinic light, the plates would certainly have been more sensitive, and the unacted-on parts would have been more soluble; thus rendering both the time of exposure and development more rapid.

After the plate was prepared and dried, it was exposed in the camera, or by superposition, under a print, or other suitable subject, that would lie flat. For the latter, an exposure of two or three hours in bright sunshine was necessary, and the former required six or eight hours in a strong light. Even those prolonged exposures did not produce a visible image, and the resultant picture was not revealed to view until after a tedious process of dissolving, for it could scarcely be called development. M. Niépce himself says, “The next operation then is to disengage the shrouded imagery, and this is accomplished by a solvent.” The solvent consisted of one measure of the essential oil of lavender and ten of oil of white petroleum or benzole. On removing the tablet from the camera or other object, it was plunged into a bath of the above solvent, and left there until the parts not hardened by light were dissolved. When the picture was fully revealed, it was placed at an angle to drain, and finished by washing it in water.

Except for the purpose of after-etching, M. Niépce’s process was of little commercial value then, but it has since been of some service in the practice of photo-lithography. That, I think, is the fullest extent of the commercial or artistic advantages derived from the utmost success of M. Niépce’s discoveries; but what he considered his failures, the fact that he employed copper plates coated with silver for his heliographic tablets, and endeavoured to darken the clean or clear parts of the silvered plates with the fumes of iodine for the sake of contrast only, may be safely accepted as the foundation of Daguerre’s ultimate success in discovering the extremely beautiful and workable process known as the Daguerreotype.

M. Niépce appears to have done very little more towards perfecting the heliographic process after joining Daguerre; but the latter effected some improvements, and substituted for the bitumen of Judea the residuum obtained by evaporating the essential oil of lavender, without, however, attaining any important advance in that direction. After the death of M. Nicéphore Niépce, a new agreement was entered into by his son, M. Isidore Niépce, and M. Daguerre, and we must leave those two experimentalists pursuing their discoveries in France while we return to England to pick up the chronological links that unite the history of this wonderful discovery with the time that it was abandoned by Wedgwood and Davy, and the period of its startling and brilliant realization.

In 1834, Mr. Henry Fox Talbot, of Lacock Abbey, Wilts, “began to put in practice,” as he informs us in his memoir read before the Royal Society, a method which he “had devised some time previously, for employing to purposes of utility the very curious property which has been long known to chemists to be possessed by the nitrate of silver—namely, to discolouration when exposed to the violet rays of light.” The statement just quoted places us at once on the debateable ground of our subject, and compels us to pause and consider to what extent photography is indebted to Mr. Talbot for its further development at this period and five years subsequently. In the first place, it is not to be supposed for a moment that a man of Mr. Talbot’s position and education could possibly be ignorant of what had been done by Mr. Thomas Wedgwood and Sir Humphry Davy. Their experiments were published in the Journal of the Royal Institution of Great Britain in June, 1802, and Mr. Talbot or some of his friends could not have failed to have seen or heard of those published details; and, in the second place, a comparison between the last records of Wedgwood and Davy’s experiments, and the first published details of Mr. Talbot’s process, shows not only that the two processes are identically the same, but that Mr. Talbot published his process before he had made a single step in advance of Wedgwood and Davy’s discoveries; and that his fixing solution was not a fixer at all, but simply a retardant that delayed the gradual disappearance of the picture only a short time longer. Mr. Talbot has generally been credited with the honour of producing the first permanent sun-pictures on paper; but there are grave reasons for doubting the justice of that honour being entirely, if at all, due to him, and the following facts and extracts will probably tend to set that question at rest, and transfer the laurel to another brow.

To the late Rev. J. B. Reade is incontestably due the honour of having first applied tannin as an accelerator, and hyposulphite of soda as a fixing agent, to the production and retention of light-produced pictures; and having first obtained an ineffaceable photograph upon paper. Mr. Talbot’s gallate of silver process was not patented or published till 1841; whereas the Rev. J. B. Reade produced paper negatives by means of gallic acid and nitrate of silver in 1837. It will be remembered that Mr. Wedgwood had discovered and stated that the chloride of silver was more sensitive when applied to white leather, and Mr. Reade, by inductive reasoning, came to the conclusion that tanned paper and silver would be more sensitive to light than ordinary paper coated with nitrate of silver could possibly be. As the reverend philosopher’s ideas on that subject are probably the first that ever impregnated the mind of man, and as his experiments and observations are the very earliest in the pursuit of a gallic acid accelerator and developer, I will give them in his own words.—“No one can dispute my claim to be the first to suggest the use of gallic acid as a sensitiser for prepared paper, and hyposulphite of soda as a fixer. These are the keystones of the arch at which Davy and Young had laboured—or, as I may say in the language of another science, we may vary the tones as we please, but here is the fundamental base. My use of gallate of silver was the result of an inference from Wedgwood’s experiments with leather, ‘which is more readily acted upon than paper’ (Journal of the Royal Institution, vol. i., p. 171). Mrs. Reade was so good as to give me a pair of light-coloured leather gloves, that I might repeat Wedgwood’s experiment, and, as my friend Mr. Ackerman reminds me, her little objection to let me have a second pair led me to say, ‘Then I will tan paper.’ Accordingly I used an infusion of galls in the first instance in the early part of the year 1837, when I was engaged in taking photographs of microscopic objects. By a new arrangement of lenses in the solar microscope, I produced a convergence of the rays of light, while the rays of heat, owing to their different refractions, were parallel or divergent. This fortunate dispersion of the calorific rays enabled me to use objects mounted in balsam, as well as cemented achromatic object glasses; and, indeed, such was the coolness of the illumination, that even infusoria in single drops of water were perfectly happy and playful (vide abstracts of the ‘Philosophical Transactions,’ December 22nd, 1836). The continued expense of an artist—though, at first, I employed my friend, Lens Aldons—to copy the pictures on the screen was out of the question. I therefore fell back, but without any sanguine expectations as to the result, upon the photographic process adopted by Wedgwood, with which I happened to be well acquainted. It was a weary while, however, before any satisfactory impression was made, either on chloride or nitrate paper. I succeeded better with the leather; but my fortunate inability to replenish the little stock of this latter article induced me to apply the tannin solution to paper, and thus I was at once placed, by a very decided step, in advance of earlier experimenters, and I had the pleasure of succeeding where Talbot acknowledges that he failed.

“Naturally enough, the solution which I used at first was too strong, but, if you have ever been in what I may call the agony of a find, you can conceive my sensations on witnessing the unwilling paper become in a few seconds almost as black as my hat. There was just a passing glimpse of outline, ‘and in a moment all was dark.’ It was evident, however, that I was in possession of all, and more than all, I wanted, and that the dilution of so powerful an accelerator would probably give successful results. The large amount of dilution greatly surprised me; and, indeed, before I obtained a satisfactory picture, the quantity of gallic acid in the infusion must have been quite homœopathic; but this is in exact accordance with modern practice and known laws. In reference to this point, Sir John Herschel, writing from Slough, in April, 1840, says to Mr. Redman, then of Peckham (where I had resided), ‘I am surprised at the weak solution employed, and how, with such, you have been able to get a depth of shadow sufficient for so very sharp a re-transfer is to me marvellous.’ I may speak of Mr. Redmond as a photographic pupil of mine, and at my request, he communicated the process to Sir John, which, ‘on account of the extreme clearness and sharpness of the results,’ to use Sir John’s words, much interested him.

“Dr. Diamond also, whose labours are universally appreciated, first saw my early attempts at Peckham in 1837, and heard of my use of gallate of silver, and was thus led to adopt what Admiral Smyth then called ‘a quick mode of taking bad pictures’; but, as I told the Admiral in reply, he was born a baby. Whether our philosophical baby is ‘out of its teens’ may be a question; at all events, it is a very fine child, and handles the pencil of nature with consummate skill.

“But of all the persons who heard of my new accelerator, it is most important to state that my old and valued friend, the late Andrew Ross, told Mr. Talbot how first of all, by means of the solar microscope, I threw the image of the object on prepared paper, and then, while the paper was yet wet, washed it over with the infusion of galls, when a sufficiently dense negative was quickly obtained. In the celebrated trial, “Talbot versus Laroche,” Mr. Talbot, in his cross-examination, and in an almost breathless court, acknowledged that he had received this information from Ross, and from that moment it became the unavoidable impression that he was scarcely justified in taking out a patent for applying my accelerator to any known photogenic paper.

“The three known papers were those impregnated with the nitrate, chloride, and the iodide of silver—the two former used by Wedgwood and Young, and the latter by Davy. It is true that Talbot says of the iodide of silver that it is quite insensitive to light, and so it is as he makes it; but when he reduces it to the condition described by Davy—viz., affected by the presence of a little free nitrate of silver—then he must acknowledge, with Davy, that ‘it is far more sensitive to the action of light than either the nitrate or the muriate, and is evidently a distinct compound.’ In this state, also, the infusion of galls or gallic acid is, as we all know, most decided and instantaneous, and so I found it to be in my early experiments. Of course I tried the effects of my accelerator on many salts of silver, but especially upon the iodide, in consequence of my knowledge of Davy’s papers on iodine in the ‘Philosophical Transactions.’ These I had previously studied, in conjunction with my chemical friend, Mr. Hodgson, then of Apothecaries’ Hall. I did not, however, use iodised paper, which is well described by Talbot in the Philosophical Magazine for March, 1838, as a substitute for other sensitive papers, but only as one among many experiments alluded to in my letter to Mr. Brayley.

“My pictures were exhibited at the Royal Society, and also at Lord Northampton’s, at his lordship’s request, in April, 1839, when Mr. Talbot also exhibited his. In my letter to Mr. Brayley, I did not describe iodised pictures, and, therefore, it was held that exhibition in the absence of description left the process legally unknown. Mr. Talbot consequently felt justified in taking out a patent for uniting my known accelerator with Davy’s known sensitive silver compound, adopting my method (already communicated to him) with reference to Wedgwood’s papers, and adding specific improvements in manipulation. Whatever varied opinion may consequently be formed as to the defence of the patent in court, there can be but one as to the skill of the patentee.

“It is obvious that, in the process so conducted by me with the solar microscope, I was virtually within my camera, standing between the object and the prepared paper. Hence the exciting and developing processes were conducted under one operation (subsequently patented by Talbot), and the fact of a latent image being brought out was not forced upon my attention. I did, however, perceive this phenomenon upon one occasion, after I had been suddenly called away, when taking an impression of the Trientalis Europæa—and surprised enough I was, and stood in astonishment to look at it. But with all this, I was only, as the judge said, “very hot.” I did not realize the master fact that the latent image which had been developed was the basis of photographic manipulation. The merit of this discovery is Talbot’s, and his only, and I honour him greatly for his skill and earlier discernment. I was, indeed, myself fully aware that the image darkened under the influence of my sensitiser, while I placed my hand before the lens of the instrument to stop out the light; and my solar mezzotint, as I then termed it, was, in fact, brought out and perfected under my own eye by the agency of gallic acid in the infusion, rather than by the influence of direct solar action. But the notion of developing a latent image in these microscopic photographs never crossed my mind, even after I had witnessed such development in the Trientalis Europæa. My original notion was that the infusion of galls, added to the wet chloride or nitrate paper while the picture was thrown upon it, produced only a new and highly sensitive compound; whereas, by its peculiar and continuous action after the first impact of light on the now sensitive paper, I was also, as Talbot has shown, employing its property of development as well as excitement. My ignorance of its properties was no bar to its action. However, I threw the ball, and Talbot caught it, and no man can be more willing than myself to acknowledge our obligations to this distinguished photographer. He compelled the world to listen to him, and he had something worth hearing to communicate; and it is a sufficient return to me that he publicly acknowledged his obligation to me, with reference to what Sir David Brewster calls ‘an essential part of his patent’ (vide North British Review, No. 14 article—‘Photography’).

“Talbot did not patent my valuable fixer. Here I had the advantage of having published my use of hyposulphite of soda, which Mr. Hodgson made for me in 1837, when London did not contain an ounce of it for sale. The early operators had no fixer; that was their fix; and, so far as any record exists, they got no further in this direction than ‘imagining some experiments on the subject!’ I tried ammonia, but it acted too energetically on the picture itself to be available for the purpose. It led me, however, to the ammonia nitrate process of printing positives, a description of which process (though patented by Talbot in 1843) I sent to a photographic brother in 1839, and a quotation from my letter of that date has already appeared in one of my communications to Notes and Queries. On examining Brande’s Chemistry, under the hope of still finding the desired solvent which should have a greater affinity for the simple silver compound on the uncoloured part of the picture than for the portion blackened by light, I happened to see it stated, on Sir John Herschel’s authority, that hyposulphite of soda dissolves chloride of silver. I need not now say that I used this fixer with success. The world, however, would not have been long without it, for, when Sir John himself became a photographer in the following year, he first of all used hyposulphite of ammonia, and then permanently fell back upon the properties of his other compound. Two of my solar microscope negatives, taken in 1837, and exhibited with several others by Mr. Brayley in 1839 as illustrations of my letter and of his lecture at the London Institution, are now in the possession of the London Photographic Society. They are, no doubt, the earliest examples of the agency of two chemical compounds which will be co-existent with photography itself, viz., gallate of silver and hyposulphite of soda, and my use of them, as above described, will sanction my claim to be the first to take paper pictures rapidly, and to fix them permanently.

“Such is a short account of my contribution to this interesting branch of science, and, in the pleasure of the discovery, I have a sufficient reward.”

These lengthy extracts from the Rev. Mr. Reade’s published letter render further comment all but superfluous, but I cannot resist taking advantage of the opportunity here afforded of pointing out to all lovers of photography and natural justice that the progress of the discovery has advanced to a far greater extent by Mr. Reade’s reasoning and experiments than it was by Mr. Talbot’s ingenuity. The latter, as Mr. Reade observes, only “caught the ball” and threw it into the Patent Office, with some improvements in the manipulations. Mr. Reade generously ascribes all honour and glory to Mr. Talbot for his shrewdness in seizing what he had overlooked, viz., the development of the latent image; but there is a quiet current of rebuke running all through Mr. Reade’s letter about the justice of patenting a known sensitiser and a known accelerator, which he alone had combined and applied to the successful production of a negative on paper. Mr. Talbot’s patent process was nothing more, yet he endeavoured to secure a monopoly of what was in substance the discovery and invention of another. Mr. Talbot was either very precipitate, or ill-advised, to rush to the Patent Office with his modification, and even at this distant date it is much to be regretted that he did so, for his rash act has, unhappily for photography, proved a pernicious precedent. Mr. Reade gave his discoveries to the world freely, and the “pleasure of the discovery” was “a sufficient reward.” All honour to such discoverers. They, and they only, are the true lovers of science and art, who take up the torch where another laid it down, or lost it, and carry it forward another stage towards perfection, without sullying its brightness or dimming the flame with sordid motives.

The Rev. J. B. Reade lived to see the process he discovered and watched over in its embryo state, developed with wondrous rapidity into one of the most extensively applied arts of this marvellous age, and died, regretted and esteemed by all who knew him, December 12th, 1870. Photographers, your occupations are his monument, but let his name be a tablet on your hearts, and his unselfishness your emulation!

The year 1838 gave birth to another photographic discovery, little thought of and of small promise at the time, but out of which have flowed all the various modifications of solar and mechanical carbon printing. This was the discovery of Mr. Mungo Ponton, who first observed and announced the effects of the sun’s rays upon bichromate of potash. But that gentleman was unwise in his generation, and did not patent his discovery, so a whole host of patent locusts fell upon the field of research in after years, and quickly seized the manna he had left, to spread on their own bread. Mr. Mungo Ponton spread a solution of bichromate of potash upon paper, submitted it under a suitable object to the sun’s rays, and told all the world, without charge, that the light hardened the bichromate to the extent of its action, and that the unacted-upon portions could be dissolved away, leaving the object white upon a yellow or orange ground. Other experimenters played variations on Mr. Ponton’s bichromate scale, and amongst the performers were M. E. Becquerel, of France, and our own distinguished countryman, Mr. Robert Hunt.

During the years that elapsed between the death of M. Niépce and the period to which I have brought these records, little was heard or known of the researches of M. Daguerre, but he was not idle, nor had he abandoned his iodine ideas. He steadily pursued his subject, and worked with a continuity that gained him the unenviable reputation of a lunatic. His persistency created doubts of his sanity, but he toiled on solus, confident that he was not in pursuit of an impossibility, and sanguine of success. That success came, hastened by lucky chance, and early in January, 1839, M. Daguerre announced the interesting and important fact that the problem was solved. Pictures in the camera-obscura could be, not only seen, but caught and retained. M. Daguerre had laboured, sought, and found, and the bare announcement of his wonderful discovery electrified the world of science.

The electric telegraph could not then flash the fascinating intelligence from Paris to London, but the news travelled fast, nevertheless, and the unexpected report of M. Daguerre’s triumph hurried Mr. Talbot forward with a similar statement of success. Mr. Talbot declared his triumph on the 31st of January, 1839, and published in the following month the details of a process which was little, if any, in advance of that already known.

Daguerre delayed the publication of his process until a pension of six thousand francs per annum had been secured to himself, and four thousand francs per annum to M. Isidore Niépce for life, with a reversion of one-half to their widows. In the midst of political and social struggles France was proud of the glory of such a marvellous discovery, and liberally rewarded her fortunate sons of science with honourable distinction and substantial emolument. She was proud and generous to a chivalrous extent, for she pensioned her sons that she might have the “glory of endowing the world of science and of art with one of the most surprising discoveries” that had been made on her soil; and, because she considered that “the invention did not admit of being secured by patent;” but avarice and cupidity frustrated her noble and generous intentions in this country, and England alone was harassed with injunctions and prosecutions, while all the rest of the world participated in the pleasure and profits of the noble gift of France.