Experiments and Observations Tending to Illustrate the Nature and Properties of Electricity

That Glass will repel and not conduct the Electricity of Glass, has been mention'd by others, who have treated of this Subject; but the Experiments to determine this Matter must be conducted with a great deal of Caution; for unless the glass Tube, intended to conduct the Electricity, be as warm as the external Air, it will seem to prove the contrary, unless in very dry Places and Seasons. Thus, I sometimes have brought a cold, though dry, Glass Tube near three Feet long into a Room, where there has been a Number of People; when upon placing the Tube upon Silk Lines, and laying some Leaf Silver upon a Card at one End and rubbing another Glass Tube at the other, the Silver has, contrary to Expectation, been thrown off as readily as from an Iron Rod. At first I was surpriz'd at this Appearance, but then conjectur'd, that it must arise from the Coldness of the Glass, condensing the floating Vapour of the Room; in Order then to obviate this, I warm'd the Tube sufficiently, and this Effect was no longer produced, but the Silver lay perfectly still.

If a Number of Pieces of finely spun Glass cut to about an Inch in Length, little bits of fine Wire of the same Length of what Metal you please, and small Cork Balls, are either put all together, or each by themselves, into a dry pewter Plate, or upon a Piece of polish'd Metal, they make in the following Manner a very odd and surprizing Appearance. Let a Man, standing upon electrical Cakes, hold this Plate in his Hand with the bits of Glass, Wire, &c. detached from each other, as much as conveniently may be; when he is electrified, let him cause a Person standing upon the Ground to bring another Plate, his Hand, or any other Non-Electric, exactly over the Plate containing these Bodies. When his Hand, &c. is about eight Inches over them, let him bring it down gently: As it comes near, in proportion to the Strength of the Electricity, he will observe the bits of Glass first raise themselves upright; and then, if he brings his Hand nearer, dart directly up and stick to it without snapping. The bits of Wire will fly up likewise, and as they come near the Hand, snap aloud; you feel a smart Stroke, and see the Fire arising from them to the Hand at every Stroke; each of these, as soon as they have discharged their Fire, falls down again upon the Plate. The Cork Balls also fly up, and strike your Hand, but fall again directly. You have a constant Succession of these Appearances as long as you continue to electrify the Man, in whose Hand the Plate is held; but if you touch any part either of the Man or Plate, the Pieces of Glass, which before were upon their Ends, immediately fall down.

Some few Years ago, Sir James Lowther brought some Bladders fill'd with inflammable Air, collected from his Coal-mines, to the Royal Society. This Air flam'd upon a lighted Candle being brought near it. This Inflammability has occasion'd many terrible Accidents. Mr. Maud, a worthy Member of this Society, made at that Time by Art, and shew'd the Society, Air exactly of the same Quality. I was desirous of knowing if this Air would be kindled by electrical Flashes. I accordingly made such Air by putting an Ounce of Filings of Iron, an Ounce of Oil of Vitriol and four Ounces of Water into a Florence Flask; upon which an Ebullition ensued, and the Air, which arose from these Materials, not only fill'd three Bladders, but also, upon the Application of the Finger of an Electrified Person, took Flame and burnt near the Top and out of the Neck of the Flask a considerable Time. When the Flame is almost out, shake the Flask and the Flame revives. You must with your Finger dipped in Water, moisten the Mouth of the Flask as fast as it is dried by the Heat within, or the Electricity will not fire it: Because the Flask being an Electric per se will not snap at the Application of the Finger, without the Glass being first made non-electric by wetting. It has sometimes happen'd, if the Finger has been applied before the inflammable Air has found a ready Exit from the Mouth of the Flask, that the Flash has fill'd the Flask, and gone off with an Explosion equal to the firing of a large Pistol, and sometimes indeed it has burst the Flask. The same Effect is produced from the Spirit of Sea Salt, as from Oil of Vitriol; but as the Acid of Sea Salt is much lighter than that of Vitriol, there is no Necessity to add the Water in this Experiment.

Those who are not much acquainted with Chemical Philosophy, may think it very extraordinary, that from a Mixture of cold Substances, which both conjunctly and separately are uninflammable, this very inflammable Vapour should be produced. In order to solve this, it may not be improper to premise, that Iron is compounded of a Metallic as well as a sulphurous Part. This Sulphur is so fix'd, that, after heating the Iron red hot, and even melting it ever so often, the Sulphur will not be disengaged therefrom: But upon the Mixture of the Vitriolic Acid, and by the Heat and Ebullition which are almost instantly produced, the Metallic Part is dissolved, and the Sulphur, which before was intimately connected therewith, being disengaged, becomes volatile. This Heat and Ebullition continues 'till the Vitriolic Acid is perfectly saturated with the Metallic Part of the Iron, and the Vapour once fired continues to flame, until this Saturation being effected, no more of the Sulphur flies off.

I have heretofore mentioned, how considerably perfectly dry Air conduces to the Success of these Experiments; but we have been lately informed by an Extract of a Letter, that Abbé Nolet was of Opinion, that they would succeed in wet Weather, provided the Tubes were made of Glass, tinged blue with Zaffer. I have procured Tubes of this Sort, but, after giving them many candid Trials, I cannot think them equal to their Recommendation. I first tried one of them in a smart Shower of Rain after a dry Day, when the Drops were large, and the Spirit fired three Times in about four Minutes; the same Effect succeeded, under the same Circumstances, from the white one; but after three or four Hours raining, when the Air was perfectly wet, I never could make it succeed. And to illustrate this Matter further, I have been able when the Weather has been very dry, with once rubbing my Hand down this blue Tube, and applying it to the End of an Iron Rod six Feet long, to throw off several Pieces of Leaf-Silver lying upon a Card at the other End of this Rod, whereas I never have been able to throw it off by any Means in very wet Weather. Besides, I am of Opinion, that after the Electrical Fire is gone from the Tube, the Tube has no Share in the conducting of it; my Sentiments on that Head I laid before you in a former Paper: For if the Silk Lines are wetted, they diffuse all the Electricity, and the same Effects happen when the Air is wet, be your Glass of what Colour it will. It may not be improper here to observe, that Zaffer, which is used by the Glass-makers and Enamellers, is made of Cobalt or Mundick calcin'd after the subliming the Flowers. This being reduced to a very fine Powder, and mixt with twice or thrice its own Weight of finely powdered Flints, is moisten'd with Water and put up in Barrels, in which it soon runs into a hard Mass and is call'd Zaffer.

A dry Sponge hanging by a Pack-thread at the End of an electrified Sword, or from the Hand of an electrified Man, gives no Signs of being made electrical; if it is well soak'd in Water, wherever it is touched, you both see and feel the electrical Sparks. Not only so, but if it is so full of Water, that it falls from the Sponge, those Drops in a dark Room, receiv'd upon your Hand, not only flash and snap, but you perceive a pricking Pain. If you hold your Hand, or any non-electrical Substances, very near, the Water which had ceased dropping when the Sponge was not electrified, drops again upon its being electrified, and the Drops fall in Proportion to the receiv'd Electricity, as though the Sponge were gently squeez'd between your Fingers. I was desirous to know if I was able to electrify a Drop of cold Water, dropping from the Sponge, enough to fire the Spirit; but after many unsuccessful Trials, I was forced to desist; because the cold Water dropping from the Sponge not only cool'd the Spirit too much, but also render'd it too weak; likewise, every Drop carried with it great Part of the Electricity from the Sponge. I then consider'd, in what Manner, I could give a Tenacity to the Water, sufficient to make the Drops hang a considerable Time, and this I brought about by making a Mucilage of the Seeds of Fleawort. A wet Sponge then, squeez'd hard and fill'd with this cold Mucilage, was held in the Hand of an electrified Man, when the Drops forced out by the Electricity, assisted by the Tenacity of the Liquor, hung some Inches from the Sponge, and by a Drop of this I fir'd not only the Spirit of Wine, but likewise the inflammable Air before mentioned, both with and without the Explosion. What an extraordinary Effect is this! That a Drop of cold Water (for the Seeds contribute nothing but add Consistence to the Water) should be the Medium of Fire and Flame.

Camphor is a vegetable Resin, and of Consequence an Electric per se. This Substance, notwithstanding its great Inflammability, will not take fire from the Finger of a Man or any other Body electrified, though made very warm and the Vapours arise therefrom in great Abundance. Because, neither Electric's per se excited, or electrified Bodies, exert their Force by snapping upon Electric's per se, though not excited. If you break Camphor small and warm it in a Spoon, it is not melted by Heat like other Resins; but if that Heat were continued it would all prove volatile. To Camphor thus warm'd, the Finger of an electrified Man, a Sword or such-like, will in snapping exert its Force upon the Spoon, and the circum-ambient Vapour of the Camphor will be fired thereby, and light up the whole Quantity exposed. The same Experiment succeeds by the repulsive Power of Electricity.

A Poker thoroughly ignited put into Spirit of Wine, or into the distilled Oil of Vegetables, produces no Flame in either; it indeed occasions the Vapours to arise from the Oil in great Abundance. But if you electrify this heated Poker, the electrical Flashes presently kindle Flame in either. The Experiment is the same with Camphor. These Experiments, as well as the following, sufficiently evince, that the electrical Fire is truly Flame, and that extreamly subtil.

I have made several Trials in order to fire Gunpowder alone, which I tried both warm and cold, whole and powder'd, but never could make it succeed; and this arises in part from its Vapours not being inflammable, and in part from its not being capable of being fir'd by Flame, unless the Sulphur in the Composition is nearly in the State of Accension. This we see by putting Gunpowder into a Spoon with rectified Spirit, which, when lighted, will not fire the Powder, 'till by the Heat of the Spoon from the burning Spirit, the Sulphur is almost melted. Likewise, if you hold Gunpowder ground very fine in a Spoon over a lighted Candle, or any other Flame, as soon as the Spoon is hot enough to melt the Sulphur, you see a blue Flame, and instantly the Powder flashes off. The same Effects are observ'd in the Pulvis fulminans, compos'd of Nitre, Sulphur, and fixed Alkaline Salt. Besides, when the Gunpowder is very dry and ground very fine, it (as you please to make the Experiment) is either attracted, or repell'd; so that in the first Case, the End of your Finger when electrified, shall be cover'd over with the Powder, though held at some Distance; and in the other, if you electrify the Powder, it will fly off at the Approach of any non-electrified Substance, and sometimes even without it. But I can at Pleasure fire Gunpowder, and even discharge a Musket, by the Power of Electricity, when the Gunpowder has been ground with a little Camphor or with a few Drops of some inflammable chemical Oil. This Oil somewhat moistens the Powder, and prevents its flying away; the Gunpowder then being warm'd in a Spoon, the electrical Flashes fire the inflammable Vapour, which fires the Gunpowder: But the Time between the Vapour firing the Powder is so short, that frequently they appear as the same and not successive Operations, wherein the Gunpowder itself seems fired by the Electricity; and indeed the first Time this Experiment succeeded, the Flash was so sudden and unexpected, that the Hand of my Assistant, who touch'd the Spoon with his Finger, was considerably scorch'd. So that there seems a fourth Ingredient necessary to make Gunpowder readily take Fire by Flame, and that such a one, as will heighten the Inflammability of the Sulphur. In common Cases the lighted Match or the little Portion of red hot Glass, which falls among the Powder, and is the Result of the Collision from the Flint and Steel, fires the Charcoal and Sulphur, and these the Nitre. But if to these three Ingredients you add a fourth, viz. a Vegetable chemical Oil, and gently warm this Mixture, the Oil by the Warmth mixes intimately with the Sulphur, lowers its Consistence, and makes it readily take fire by Flame. In these Operations, notwithstanding I always made use of the finest scented Oils of Orange Peel, Lemons, and such like, yet upon the least warming the Mixture, the rank Smell of Balsam (i. e. the ready Solution) of Sulphur was very obvious.

Read before the R. S.Oct. 24. 1745.

A Continuation of the Above

Read, Feb. 6. 1745.

As Water is a non-electric, and of Consequence a Conductor of Electricity, I had Reason to believe that Ice was endowed with the same Properties. Upon making the Experiment I found my Conjectures not without Foundation; for upon electrifying a Piece of Ice, wherever the Ice was touched by a non-electric, it flashed and snapped. A Piece of Ice also held in the Hand of an electrified Man, as in the beforementioned Processes, fired warm Spirit, chemical vegetable Oils, Camphor, and Gunpowder prepared as before. But here great Care must be taken, that by the Warmth of the Hand, or of the Air in the Room, the Ice does not melt; if so, every Drop of Water therefrom considerably diminishes the received Electricity. In Order to obviate this, I caused my Assistant, while he was electrifying, to be continually wiping the Ice dry upon a Napkin hung to the Buttons of his Coat, and this being electrified as well as the Ice, prevented any Loss of the Force of the Electricity. The Experiment will succeed likewise, if, instead of the Ice, you electrify the Spirit, &c. and bring the Ice not electrified near them. I must observe, that Ice is not so ready a Conductor of Electricity as Water; so that I very frequently have been disappointed in endeavouring with it to fire inflammable Substances, when it has been readily done by a Sword or the Finger of a Man.

In the first Paper3 I had the Honour to lay before you upon this Subject, I took Notice of my having observed two different Appearances of the Fire from electrified Substances; viz. those large bright Flashes, which may be procured from any Part of electrified Bodies, by bringing a Non-Electric unexcited near them, and with which we have fired all the inflammable Substances mentioned in the Course of these Observations; and those, like the firing of wet Gunpowder, which are only perceptible at the Points or Edges of excited Non-electrics. These last also appear different in Colour and Form according to the Substances from which they proceed: For from polished Bodies, as the Point of a Sword, a Silver Probe, the Points of Scissors, and the Edges of the Steel-bar made Magnetical by the ingenious Dr. Knight, the electrical Fire appears like a Pencil of Rays, agreeing in Colour with the Fire from Boyle's Phosphorus; but from unpolished Bodies, as the End of a Poker, a rusty Nail or such-like, the Rays are much more red. The Difference of Colour here, I am of Opinion, is owing rather to the different Reflection of the electrical Fire from the Surface of the Body from which it is emitted, than to any Difference in the Fire itself. These Pencils of Rays issue successively as long as the Bodies, from which they proceed, are exciting; but they are longer and more brilliant, if you bring any Non-Electric not excited near them, though it must not be close enough to make them snap. If you hold your Hand at about two or three Inches Distance from these Points, you not only feel successive Blasts of Wind from them, but hear also a crackling Noise. Where there are several Points, you observe at the same Time several Pencils of Rays.

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It appears from Experiments, that besides the several Properties, that Electricity is possess'd of peculiar to itself, it has some in common with Magnetism and Light.

Proposition I

In common with Magnetism, Electricity counteracts, and in light Substances overcomes the Force of Gravity. Like that extraordinary Power likewise, it exerts its Force in Vacuo as powerfully as in open Air, and this Force is extended to a considerable Distance through various Substances of different Textures and Densities.

Corollary

Gravity is the general Endeavour and Tendency of Bodies towards the Center of the Earth; this is overcome by the Magnet with Regard to Iron, and by Electricity with Regard to light Substances both in its Attraction and Repulsion; but I have never been able to discern that vortical Motion, by which this Effect was said to be brought about by the late Dr. Desaguliers and others, having no other Conception of its Manner of acting than as Rays from a Center, which indeed is confirmed by several Experiments. One of which, very easy to be tried, is, that if a single downy Seed of Cotton Grass is dropped from a Man's Hand, and in its Fall comes within the Attraction of the rubbed Tube; the Down of this Seed, which before seemed to stick together, separates, and forms Rays round the Center of the Seed: Or if you fasten many of these Seeds with Mucilage of Gum Arabic, round a Bit of Stick, the Down of them when electrified, which otherwise hangs from the Stick, is raised up, and forms a circular Appearance round the Stick. As these light Bodies are directed in their Motions, only by the Force impressed upon them, and as their Appearance is constantly radiatim, such Appearance by no Means squares with our Idea of a Vortex. Some have imagined a Polarity also, when they have observed one end of an excited Glass Tube repel light Substances, and the other attract them. But this Deception, arising from the whole Length of the Tube not being excited, but only such Part of it as has been rubbed; so that as much of the Tube as is held in the Hand, remains in an unexcited State, and permits light Substances to lie still thereon, though forcibly repell'd at the other End. This attractive Power of Electricity acts not only upon Non-electrics, as Leaf-Gold, Silver, Thread, and such like, but also upon originally Electrics, as Silk, dry Feathers, little Pieces of Glass and Resin; it attracts all Bodies, that are not of the same Standard of Electricity, (if I may be allowed the Expression) as the excited Body from which it proceeds. I have found no Body however dense, whose Pores are not pervious to Electricity by a proper Management, not even Gold itself.

Proposition II

In common with Light, Electricity pervades Glass, but suffers no Refraction therefrom; I having from the most exact Observations found its Direction to be in right Lines, and that through Glasses of different Forms, included one within the other, and large Spaces left between each Glass.

Corollary

This rectilineal Direction is observable only as far as the Electricity can penetrate through unexcited Originally-electrics, and those perfectly dry; nor is it at all material, whether these Substances are transparent, as Glass; semidiaphanous, as Porcelain or thin Cakes of white Wax; or quite opake, as thick woollen Cloth, as well as woven Silk of various Colours; it is only necessary that they be Originally-electrics. But the Case is widely different with Regard to Non-electrics; wherein the Direction, given to the Electricity by the excited originally-electric, is alter'd as soon as it touches the Surface of a Non-electric, and is propagated with a Degree of Swiftness scarcely to be measured in all possible Directions to impregnate the whole Non-electric Mass in Contact with it, or nearly so, however different in itself, and which must of Necessity be terminated by an originally Electric, before the Electricity exerts the least Attraction, and then this Power is observed first at that Part of the Non-electric the most remote from the originally-electric. Thus for Example, by an excited Tube held over it, Leaf Gold will be attracted through Glass, Cloth, &c. held horizontally in the Hand of a Man standing upon the Floor, and this Attraction is exerted to a considerable Distance. On the contrary, the rubbed Tube will not attract Leaf Gold or other light Bodies, however near, through Silver, Tin, the thinnest Board, Paper, or any other Non-electric, held in the Manner before-mentioned. But if you rub the Paper over with Wax melted, and by that Means introduce the originally-electric therein, you observe the Electricity acts in right Lines, and attracts powerfully. And here I must beg Leave to remind you, not only of the former Corollary, but of some of the former Experiments also; by which it appears, that although, to make a Non-electric exert any Power, we must excite the whole Mass thereof, yet we can excite what Part, and what only, of an originally-electric we please. Thus we observe, that Leaf-gold, and the Seed of Cotton-grass, (which grows upon Boggs and is a very proper Subject for these Inquiries) are attracted under a Glass Jar made warm3, and turned Bottom upwards, upon which are placed Books and several other Non-electrics; and that the Motions of the light Bodies underneath correspond with the Motions of the Glass Tube held over them, the Electricity seeming instantaneously to pass through the Books and the Glass. But this does not happen, till the Electricity has fully impregnated the Non-electrics, which lie upon the Glass, which received Electricity is stopped by the Glass, and then these Non-electrics dart their Power directly through the upper Part of the Glass after the Manner of Originally-electrics. But if the thinnest Non-electric, even the finest Paper, as I before mentioned, is held in the Hand of a Man at the smallest Distance over the Leaf-Gold, and the Electricity is not stopped, not the least Power will be exerted, and the Gold will lie still. I must here remark likewise, that this Law of Electricity is so constant and regular, that I have not found one Deviation from it; so that even the Quicksilver, spread thin as it usually is at the Back of a Plate of a Looking-glass, will prevent the passing through of the electrical Attraction, unless stopped by an Originally-electric. This Penetration of the electrical Power through originally-electrics is much greater than has hitherto been imagined, and has caused the Want of Success to great Numbers of Experiments. I have been at no small Pains to determine, how far this Power can penetrate through a dry Originally-electric; and have found by repeated Trials, that either in a Cake of Wax alone, or of Wax and Resin mixed, when the Electricity is very powerful, it has passed, I say, in straight Lines through these Cakes of the Thickness of 2 Inches and 4/10; but I never could make it act through one of 2 Inches 8/10, for in this it was perfectly stopped. So that the Cakes commonly made use of to stop the Electricity, by being too thin, suffer a considerable Quantity of the electrical Power to pervade them, and be lost in the Floor. I make no Doubt, if the electrical Power could be more increased, it would penetrate much further through these Originally-electric Bodies.

Proposition III

Electricity, in common with Light likewise, when its Forces are collected and a proper Direction given thereto upon a proper Object, produces Fire and Flame.

COROLLARY

The Fire of Electricity (as I have before observed) is extremely delicate, and sets on Fire, as far as I have yet experienced, only inflammable Vapours. Nor is this Flame at all heightned by being superinduced upon an Iron Rod, red hot with coarser culinary Fire, as in a preceeding Experiment; nor diminished by being directed upon cold Water. However I was desirous of knowing, if this Flame would be effected by a still greater Degree of Cold; and in order to determine this, I made an artificial Cold; by which the Mercury, in a very nice Thermometer adjusted to Fahrenheit's Scale, was depressed in about 4 Minutes from 15 Degrees above the freezing Point to 30 Degrees below it, that is, the Mercury fell 45 Degrees. From this cold Mixture, when electrified, the Flashes were as powerful and the Stroke as smart as from the red hot Iron. I could have made the Cold more intense, but the above was sufficient for my Purpose. This Experiment seems to indicate, that the Fire of Electricity is affected neither by the Presence or Absence of other Fire. For as red hot Iron, by Sir Isaac Newton's Scale of Heat, is fixed at 192 Degrees, and as the Ratio between Sir Isaac's Degrees and Fahrenheit's is as 34 to 180, it necessarily follows, that the Difference of Heat between the hot Iron and the cold Mixture is 1040 Degrees; and nevertheless this vast Difference makes no Alteration in the Appearance of the electrical Flame. We find likewise, that as the Fire, arising from the Refraction of the Rays of Light by a Lens, and brought to a Focus, is observed first at some small Distance from their Surfaces, to set on Fire combustible Substances; the same Effect, as I have before observ'd, is produced in like Manner by electrical Flame.